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Dielectric Response of Nanoscopic Spherical Colloids in Alternating Electric Fields: A Dissipative Particle Dynamics Simulation

机译:纳米球形胶体在交替电路中的介电响应   电场:耗散粒子动力学模拟

摘要

We study the response of single nanosized spherical colloids in electrolytesolution to an alternating electric field (AC field) by computer simulations.We use a coarse-grained mesoscopic simulation approach that accounts in fullfor hydrodynamic and electrostatic interactions as well as for thermalfluctuations. The solvent is modeled as a fluid of single Dissipative ParticleDynamics (DPD) beads, and the colloidal particle is modeled as a rigid bodymade of DPD beads. We compute the mobility and the polarizability of a singlecolloid and investigate systematically the effect of amplitude and frequency ofthe AC-fields. Even though the thickness of the Debye layer is not "thin"compared to the radius of the colloid, and the thermal fluctuations aresignificant, the results are in good agreement with the theoretical predictionof the Maxwell-Wagner-O'Konski theory, especially for uncharged colloids.
机译:我们通过计算机模拟研究电解质溶液中单个纳米球形胶体对交变电场(AC场)的响应。我们使用了一种粗粒度介观模拟方法,该方法充分考虑了流体动力和静电相互作用以及热波动。溶剂被建模为单个耗散粒子动力学(DPD)珠粒的流体,而胶体粒子被建模为由DPD珠粒制成的刚体。我们计算单个胶体的迁移率和极化率,并系统地研究交流场的振幅和频率的影响。即使Debye层的厚度与胶体半径相比并不“薄”,并且热波动很大,但结果与Maxwell-Wagner-O'Konski理论的理论预测相吻合,特别是对于不带电的情况胶体。

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